
There are many cities throughout the world that use double-decker buses, even in Asia, Africa and South America. If you have boarded any of these buses, I don't think it is that much different from the London ones.
The double-decker bus is more favorable than the articulated bus, because it is shorter in length, therefore safer and easier to maneuver on London's narrow streets. It also has a bigger seating capacity.
To get the best view, choose the front seat on the top deck. But in the event of collisions with a bridge, you'll also be the first one to go.